Application of Ecological Footprint Analysis on nectarine production: methodological issues and results from a case study in Italy

Ecological Footprint Analysis (EFA) is an environmental accounting system that provides an aggregate indicator which is both scientifically robust and easy to understand by non-experts. Although based on the lifestyle consumption of natural resources, recent improvements in the methodology now allow the application of EFA to a final product. Thus the resulting footprint value represents the environmental cost of all of the activities required to create, use and/or dispose of a particular product. The application of EFA to agricultural systems is still uncommon and examples in the fruit sector rare. In this work a detailed application of EFA to a commercial nectarine orchard in Piedmont (Italy) is presented. In contrast to previous studies, we considered not only the one-year field operations, but also the whole lifetime of the orchard. The calculation was conducted for six different orchard stages: (ST1) nursery propagation of the young plants; (ST2) orchard establishment, (ST3) young trees producing low yields, (ST4) mature trees at full production, (ST5) declining trees with low yields, and finally (ST6) orchard removal. The environmental costs at each stage are presented and related to each other on the basis of the relative footprint value. Results highlight the importance of applying EFA to the entire lifecycle of orchard production: ST4 accounted for the majority of costs at 65% followed by ST2, ST3 and ST5 at or near 10%, whilst the costs of ST1 and ST6 were negotiable. Thus it is the type of ST4 production used which can have the greatest impact on EFA values.     

The annual course of TCA formation in the lower troposphere: a modeling study

We present a modeling study investigating the influence of climate conditions and solar radiation intensity on gas-phase trichloroacetic acid (TCA) formation. As part of the ECCA-project (Ecotoxicological Risk in the Caspian Catchment Area), this modeling study uses climate data specific for the two individual climate regimes, namely "Kalmykia" and "Kola Peninsula". A third regime has also been included in this study, namely "Central Europe", which serves as a reference to somehow more moderate climate conditions. The simulations have been performed with a box modeling package (SBOX, photoRACM), which uses Regional Atmospheric Chemistry Mechanism (RACM) as its chemistry scheme. For this model a mechanism supplement has been developed including the reaction pathways of methyl chloroform photooxidation. The investigations are completed by a detailed sensitivity study addressing the impact of temperature and relative humidity. Atmospheric OH and HO2 concentrations and the NOx/HO2 ratio were identified as the governing quantities controlling the TCA formation trough methyl chloroform oxidation in the gas phase. Model calculations show a TCA production rate ranging between almost zero and 6.5 x 10(3) molecules cm(-3) day(-1) depending on location and season. In the Kalmykia regime the model predicts mean TCA production rates of 1.3 x 10(-4) and 5.4 x 10(-5) microg m(-3) year(-1) for the urban and rural environment, respectively. From the comparison of model calculations with measured TCA burdens in the soil ranging between 130 g m(-3) and 1750 g m(-3) we conclude that TCA formation through methyl chloroform photooxidation in the gas-phase is probably not the principal atmospheric TCA source in this region.     

Glacial-interglacial changes in the occurrence of Pb, Cd, Cu and Zn in Vostok Antarctic ice from 240 000 to 410 000 years BP

Lead (Pb), cadmium (Cd), copper (Cu) and zinc (Zn) have been measured by electrothermal atomic absorption spectrometry in various sections of the 3623 m deep ice core drilled at Vostok, in central East Antarctica. The sections were dated from 240 to 410 kyear BP (Marine Isotopic Stages (MIS) 7.5 to 11.3), which corresponds to the 3rd and 4th glacial-interglacial cycles before present. Concentrations are found to have varied greatly during this 170 kyear time period, with high concentration values during the coldest climatic stages such as MIS 8.4 and 10.2 and much lower concentration values during warmer periods, such as the interglacials MIS 7.5, 9.3 and 11.3. Rock and soil dust were the dominant sources for Pb, whatever the period, and for Zn and Cu and possibly Cd during cold climatic stages. The contribution from volcanic emissions was important for Cd during all periods and might have been significant for Cu and Zn during warm periods.